用可塑化剂进行自愈结合器系统的无溶剂固化,用于能量材料
Minghao Zhang1, Xudong Hou1, Qifa Yao1
1School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
Polymers
|October 16, 2025
概括
一种新的无溶剂方法增强了使用二甲 (DBP) 的能量材料的自我愈合结合剂. 这种方法提高了可靠性和能量密度,使无空无空的推进剂颗粒具有快速裂愈合能力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 能量材料 能量材料
背景情况:
- 用于能量材料的自愈结合剂的溶剂处理限制了可靠性和能量密度.
- 开发无溶剂制造路线对于提高材料的能量性能至关重要.
研究的目的:
- 为了建立一个无溶剂固化路径Diels-Alder自我愈合的聚丁结合剂.
- 调查二甲 (DBP) 作为功能性增塑剂和分散剂的作用.
- 为了证明这种粘合剂系统在制造自愈固体推进剂中的应用.
主要方法:
- 使用富拉尼尔终结的聚乙烯结合剂与二甲 (DBP) 作为外部增塑剂.
- 采用无溶剂固化工艺来实现交联网络的形成.
- 使用开发的粘合剂系统制造了80%重量%固体含量的固体推进剂.
主要成果:
- 用DBP塑化的粘合膜在120°C时在5分钟内显示出预切割裂的自我愈合.
- 在60°C下24小时后,机械性能几乎完全恢复.
- 无溶剂的造固体推进剂颗粒是密集的,没有空隙,并迅速治愈表面裂.
结论:
- 一种功能性塑化剂,DBP,可以使自愈的聚丁结合剂无溶剂固化.
- 这种方法克服了基于溶剂的能量材料的加工限制.
- 开发的粘合剂系统为制造可靠的,自我愈合的能量材料和推进剂提供了可行的途径.
相关概念视频
Superplasticizers
302
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
302
Accelerated Curing of Concrete
439
Accelerating concrete curing is achieved by applying heat and additional moisture. This process accelerates the hydration of the cement, resulting in an earlier strength gain in the concrete. Steam curing is a method wherein the concrete products are either transported through a chamber on a conveyor belt or encased in plastic, allowing steam at atmospheric pressure to circulate freely around them. This process begins with a phase of moist curing that typically lasts between 3 to 5 hours, after...
439
Plasticizers
333
Water-reducers, or plasticizers, are chemical admixtures used in concrete to improve strength and workability. These additives reduce the water-cement ratio without compromising workability, lower the cement content while maintaining the same workability, or increase workability to assist concrete placement in inaccessible areas.
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
333
Curing of Concrete
349
The hydration of cement takes place within the water-filled capillary pores. However, environmental elements can disrupt this process by evaporating water from the concrete surfaces. Sealed concrete with a water-cement ratio below 0.5 experiences self-desiccation, leading to water loss. The water loss in concrete is mitigated by curing. This technique involves keeping the concrete saturated to maintain the necessary temperature and moisture conditions, to optimally fill the spaces in the cement...
349
Curing Methods
280
Concrete members with a small surface-to-volume ratio are cured by oiling and moistening the forms before casting the concrete member. These forms can be left in place for a prolonged period to prevent moisture loss, and can be wetted if made of a material suitable for wetting. If the forms are removed early, the concrete member is moistened and covered with polythene sheets to maintain moisture. For large horizontal concrete surfaces exposed to dry weather, a temporary covering is suspended...
280
Waterproofing and Anti-Bacterial Admixtures in Concrete
223
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
223


