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Updated: Jan 15, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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新的复合物与不对称的胺-胺连接体:合成,表征和催化中的应用

Fernando Gómez Zamorano1,2, María José Rojas2, Sonia Mallet-Ladeira3

  • 1Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France.

Molecules (Basel, Switzerland)
|October 16, 2025
PubMed
概括

一种新型的复合物与胺-胺连接体有效催化二氧化碳 (CO2) 和环氧化物转化为循环碳酸盐. 与辅助催化剂一起的二甲基化复合物 (AlMe2L) 在温和条件下显示出最高的效率.

关键词:
合金复合体的复合体不对称的阿米丁胺连接体催化剂是一种催化剂.

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Primary amines react with carbonyl compounds—aldehydes and ketones—to generate imines. Imines consist of a C=N double bond and are named Schiff bases after its discoverer—the German chemist Hugo Schiff. On the other hand, secondary amines react with carbonyl compounds to give enamines. In enamines, the presence of a C=C double bond adjacent to the nitrogen atom leads to the delocalization of the lone pair.
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