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Updated: Jan 15, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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通过二cyclopentadienyltitanium ((III) 介导的灾难选择性改革特斯基反应

Josefa L López-Martínez1, Irene Torres-García1, Manuel Muñoz-Dorado1

  • 1Organic Chemistry, University of Almería, CIAIMBITAL, 04120 Almería, Spain.

Molecules (Basel, Switzerland)
|October 16, 2025
PubMed
概括

一种新的催化剂,二cyclopentadienyltitanium(III) (CpTiCl2),可以实现立体选择性的Reformatsky反应. 这种方法有效地创建具有高合成选择性的碳-碳键,推进复杂分子合成.

关键词:
在CpTiCl2中.这是改革派的反应.交叉合反应的反应它们具有 diastereoselectivity 的选择性.这是β-基 Ester.

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