在地表水中对疏水性和亲水性有机化合物的平衡和动态被动取样方面的成就和挑战
Kees Booij1, Rachel Mackie2, Branislav Vrana3
1PaSOC, 8821 LV Kimswerd, The Netherlands.
概括
通过被动取样,有效地监测地表水中的有机化学物质. 动态采样对于时间变化的度是理想的,而平衡采样适用于稳定的条件,提供准确的风险评估.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
背景情况:
- 被动采样对于监测和评估地表水中有机化学品的风险至关重要.
- 采样器设计侧重于不同度变异的平衡或动态采样.
研究的目的:
- 为了比较地表水中的有机化学品的平衡和动态被动采样方法.
- 突出每个方法在准确性和错误来源方面的优缺点.
- 评估水友性化合物的被动采样的进展和未来方向.
主要方法:
- 均衡和动力抽样原理的理论比较.
- 分析每个采样方法的主导错误来源 (采样机-水和采样率).
- 综述了水友性化合物被动采样运输建模方面的进展.
主要成果:
- 均衡和动力抽样都对时间稳定的度准确.
- 动力取样对于与水友性化合物共同的时间可变度是有利的.
- 主导误差不同:取样器-水吸附用于平衡,取样率用于动力.
结论:
- 被动采样方法提供了准确的环境监测.
- 建议使用扩散细胞进行进一步的研究,以改善水友性化合物被动采样.
- 通过不同层的运输建模的进步是成熟的被动水采样技术的关键.
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