开发一种经验证的基于 CO2 吸收率的模型,用于使用 Aspen Plus 在水性 2‐Amino-2-methyl-1-propanol 和 Piperazine 混合物中的吸收
Diego Morlando1, Ying Zhang2, Shu Wang3
1Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim N-7491, Norway.
概括
一个新的热力学模型准确地预测了氨基溶液中的二氧化碳吸收,这对于碳捕获技术至关重要. 该框架提高了使用2-amino-2-methyl-1-propanol和piperazine混合物捕获二氧化碳的工艺设计和效率.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 热力学是一种热力学.
- 碳捕获技术的技术
背景情况:
- 使用氨基溶液吸收二氧化碳 (CO2) 是燃烧后碳捕获的关键技术.
- 2-氨基-2-甲基-1-醇 (AMP) 和皮佩拉 (PZ) 的水性混合物是有前途的吸收剂,因为它们具有有利的特性.
- 精确的热力学模型对于优化二氧化碳捕获过程的设计和运行至关重要.
研究的目的:
- 开发和验证一个新的e-NRTL热力学框架,用于模拟水性AMP/PZ混合物中的二氧化碳吸收.
- 准确预测二氧化碳的溶解度,总压力,吸收热量和自由二氧化碳度.
- 评估模型在各种操作条件和氨基度的性能.
主要方法:
- 在Aspen Plus开发一个e-NRTL热力学框架,用于CO2-AMP-PZ-H2O系统.
- 适应模型参数,使用实验数据对不同的AMP和PZ度,温度和CO2负载进行调整.
- 用试点规模的竞选数据验证模型,包括质量转移和动力学.
主要成果:
- 通过e-NRTL模型, CO2 溶解度的绝对平均相对偏差 (AARD) 为 26.3%,总压力为 7.0%.
- 该模型准确地预测了吸收热量 (AARD 10.2%) 和自由二氧化碳度 (AARD 13.1%).
- 对二氧化碳捕获,丰富装载和再沸器的基于速率的模型预测在试点活动数据的5%AARD范围内.
结论:
- 开发的e-NRTL热力学框架提供了水性AMP/PZ溶液中二氧化碳吸收的强大而准确的表示.
- 该模型显示了与工业二氧化碳捕获应用相关的关键过程变量具有良好的预测能力.
- 经过验证的模型,加上质量转移和动力学,适用于设计和优化大型碳捕获设施.
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