雨水控制措施中的PFAS:清除,分配和长期命运
César Gómez-Ávila1, Tariq Hussain2, Balaji Rao2
1Texas Tech University, Department of Chemical Engineering, Lubbock, TX, USA.
Water research
|October 18, 2025
概括
传统的雨水控制措施 (SCM) 在去除和多基物质 (PFAS) 方面表现出有限的有效性. 大多数PFAS留在过水中,突出了处理这些持久污染物的挑战.
科学领域:
- 环境化学环境化学
- 水质管理水质管理
- 污染物运输 污染物运输
背景情况:
- 和多醇基物质 (PFAS) 是在各种环境矩阵中发现的持久性有机污染物.
- 传统的雨水控制措施 (SCM) 被广泛用于改善水质,但它们对PFAS的有效性尚不清楚.
- 雨水中的PFAS污染对水生生态系统构成风险,并可能通过再利用水对人类健康构成风险.
研究的目的:
- 评估不同传统的SCM在从雨水中去除一系列PFAS化合物的性能.
- 在SCM中,研究PFAS在颗粒物和过水相之间的分区行为.
- 在一年的时间内评估PFAS在保留池SCM中的转化和积累潜力.
主要方法:
- 对雨水流入,废水和SCM中的26种不同的PFAS化合物的分析.
- PFAS与悬浮固体和过水 (<0.7微米) 的关联的表征.
- 在一年内对保留池的SCM进行监测,包括对前体化合物,稳定产品和沉积物的分析.
主要成果:
- 碳链较长 (≥C9) 的PFAS与较短链 (≤C8) 相比,对颗粒物有更高的亲和力.
- 大多数传统的SCM显示过水PFAS的去除能力较差 (<0.7μm),其中一些显示PFAS度意外增加.
- 一个保留池显示了一些颗粒物PFAS的去除和PFAS前体的现场转化证据,但由于蒸发而增加过水PFAS度.
结论:
- 传统的SCM在很大程度上无法有效地去除PFAS的重要过水分数.
- PFAS可以在SCM中的沉积物中持久,转化和积累,特别是保留池.
- 在雨水中有效管理PFAS需要超越传统SCM的先进处理策略.
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