氨基环氧系统在各种固化后温度下的机械和热性能数据
Alex Tamayo-Aguilar1, Víctor H Guerrero1, Patricia I Pontón1
1Department of Materials, Escuela Politécnica Nacional, Quito 170109, Ecuador.
Data in brief
|October 20, 2025
概括
为高温应用量身定制氨基环氧系统至关重要. 优化后固化温度显著提高机械和热性能,确保在苛刻的行业可靠的性能.
科学领域:
- 材料科学与工程 材料科学与工程
- 聚合物化学 聚合物化学
- 机械工程 机械工程
背景情况:
- 氨基环氧热系统被广泛用于苛刻的应用.
- 控制热和机械性能对于高温性能至关重要.
- 固化后处理显著影响环氧系统的最终性能.
研究的目的:
- 为量身定制的氨基环氧系统开发制造指南.
- 研究固化后温度对机械和热性能的影响.
- 为高温应用建立可重复性质.
主要方法:
- 使用了一种商用环氧系统 (Epikure 3223 amine/Epon 828环氧).
- 标本经过室温固化,然后在80,100和120°C进行后固化.
- 使用动态机械分析 (DMA) 和柔性测试来评估机械性能.
- 热行为通过差分扫描热量计 (DSC),热力学分析 (TMA) 和热重力学分析 (TGA) 来评估.
- 使用统计分析 (ANOVA) 来确定财产的意义.
主要成果:
- 固化后的温度对环氧系统的机械和热性能产生重大影响.
- 优化后固化扩展了玻璃状态的操作温度范围.
- 在接近玻璃过渡温度 (Tg ∞ ≈ 153 °C) 的温度下,可以达到可重现的性能.
结论:
- 选择合适的后固化工艺对于提高环氧系统性能至关重要.
- 这种方法可确保在汽车,航空航天和建筑领域的高温应用中具有可预测和可靠的性能.
- 这种方法将固化动力学与环氧系统的热史分开.
更多相关视频
07:15A Testing Platform for Durability Studies of Polymers and Fiber-reinforced Polymer Composites under Concurrent Hygrothermo-mechanical Stimuli
Published on: December 11, 2014
14.2K
07:02The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
Published on: August 25, 2016
14.2K
相关概念视频
Physical Properties of Amines
4.1K
Amines with low molecular weight are usually gaseous at room temperature, while those with high molecular weight are liquid or solids in nature. Usually, low molecular weight amines have a rotten fish-like smell. Diamines typically have a pungent smell. For instance, cadaverine and putrescine, depicted in Figure 1, are two molecules responsible for decaying tissue.
4.1K
Accelerated Curing of Concrete
439
Accelerating concrete curing is achieved by applying heat and additional moisture. This process accelerates the hydration of the cement, resulting in an earlier strength gain in the concrete. Steam curing is a method wherein the concrete products are either transported through a chamber on a conveyor belt or encased in plastic, allowing steam at atmospheric pressure to circulate freely around them. This process begins with a phase of moist curing that typically lasts between 3 to 5 hours, after...
439
Curing Methods
280
Concrete members with a small surface-to-volume ratio are cured by oiling and moistening the forms before casting the concrete member. These forms can be left in place for a prolonged period to prevent moisture loss, and can be wetted if made of a material suitable for wetting. If the forms are removed early, the concrete member is moistened and covered with polythene sheets to maintain moisture. For large horizontal concrete surfaces exposed to dry weather, a temporary covering is suspended...
280
Curing of Concrete
349
The hydration of cement takes place within the water-filled capillary pores. However, environmental elements can disrupt this process by evaporating water from the concrete surfaces. Sealed concrete with a water-cement ratio below 0.5 experiences self-desiccation, leading to water loss. The water loss in concrete is mitigated by curing. This technique involves keeping the concrete saturated to maintain the necessary temperature and moisture conditions, to optimally fill the spaces in the cement...
349
Cold Weather Concreting
358
When freshly poured concrete is exposed to freezing temperatures before it has set, the water within the concrete can freeze. This expansion disrupts the setting process, delays chemical reactions necessary for hardening, and increases the volume of pores within the hardened concrete, which weakens its overall structure. If the concrete manages to reach an appreciable strength before it freezes, the damage can be somewhat mitigated.
To counteract the negative impacts of cold weather, ensuring...
To counteract the negative impacts of cold weather, ensuring...
358
Physical Properties of Ethers
8.3K
Overview
An ether molecule has a net dipole moment due to the polarity of C–O bonds. Subsequently, boiling points of ethers are lower than those of alcohols of comparable molecular weight and slightly higher than those of hydrocarbons of comparable molecular weight (Table 1).
Ethers can act as hydrogen bond acceptors, making them more water-soluble than hydrocarbons, but since ethers cannot act as hydrogen bond donors, they are much less soluble in water than alcohols. Ethers are considered...
An ether molecule has a net dipole moment due to the polarity of C–O bonds. Subsequently, boiling points of ethers are lower than those of alcohols of comparable molecular weight and slightly higher than those of hydrocarbons of comparable molecular weight (Table 1).
Ethers can act as hydrogen bond acceptors, making them more water-soluble than hydrocarbons, but since ethers cannot act as hydrogen bond donors, they are much less soluble in water than alcohols. Ethers are considered...
8.3K
