释放生物炭的碳基组:Fe-Mn氧化物协同作用使得高效的As (III) 固定通过非激进氧化
Zihang Cheng1, Yilin Wu1, Ruiqi Du2
1School of Environment and Chemical Engineering, Foshan University, Foshan, 528225, China.
用铁氧化物修改的生物炭有效地从水中去除有毒的化 (As(III)). 这种新的方法增强了吸附和氧化,使不移动,使水更安全.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 水中的化物 (化物) 污染是全球关键的健康问题.
- 铁 (Fe-Mn) 改性生物炭对酸吸附有希望,但协同作用机制需要进一步研究.
研究的目的:
- 探索Fe-Mn氧化物和生物炭之间的协同作用,以提高As (III) 的去除.
- 研究Fe-Mn改性生物炭的吸附机制和性能.
主要方法:
- 合成的Fe-Mn氧化物 (Fe3O4 / MnO2复合物和MnFe2O4) 加载生物炭 (Fe-MnOBC和FeMnOBC).
- 研究了As(III) 吸附动力学和异热物.
- 利用光谱技术 (EPR,XPS) 阐明吸附和氧化机制.
主要成果:
- 对于,FeMnOBC具有241.6mg/g的高最大吸附能力.
- 吸附之后是化学吸收,具有伪二阶 (Fe-MnOBC) 和埃洛维奇 (FeMnOBC) 动力学.
- (III) 通过内部球体复合吸附,由Mn (IV) /Mn (III) 氧化为 (V),并由C=O组固定.
结论:
- 铁氧化物增强生物炭对酸的吸附和氧化能力.
- C=O功能组在固定中发挥着关键作用,这是一个以前被忽视的机制.
- 这项研究为设计用于有毒元素修复的先进生物炭提供了洞察力.
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