在受压缩疲劳影响的聚氨弹性体中,热机械驱动的等级进化.
Min Wang1,2, Yushu Tian1,2, Jihang Yu1,2
1State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China.
ACS applied materials & interfaces
|October 20, 2025
概括
具有高微相分离的聚氨弹性体 (PUE) 通过管理热量和保持结构完整性来抵抗疲劳. 低分离PUE由于热量积累和结构崩而更快地失效.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 机械工程 机械工程
背景情况:
- 聚氨弹性体 (PUE) 对于苛刻的应用至关重要,但由于热量的积累,在压力疲劳下降解.
- 在疲劳下PUE的热量,机械和微观结构变化之间的复杂相互作用尚未完全理解.
研究的目的:
- 研究在循环压缩下不同程度的微相分离的PUE的热力学行为和微结构演变.
- 为设计耐疲劳的PUE建立结构-属性关系.
主要方法:
- 设计和合成具有低 (LP) 和高 (HP) 微相分离的PUE.
- 同步温度场监测和多尺度表征技术.
- 在循环压缩下分析微观结构变化 (硬段域,球体).
主要成果:
- LP-PUE 呈现出快速的热量积累,无序的硬段域和球状岩碎片,导致结构崩和17.2%的压缩.
- 在HP-PUE中,通过叶片重定向和受控的球状岩碎片,证明了应力分布,从而保持了结构完整性.
- HP-PUE显示出优越的疲劳耐用性,压缩设置明显较低 (6.2%).
结论:
- 该研究阐明了基于微相分离的PUE中独特的热力学进化途径.
- 建立了一个明确的结构-属性关系,强调了有序硬段网络对于耐疲劳性的重要性.
- 这些发现为设计高压力应用的先进PUE提供了基础,提高了耐久性.
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