使用酸从红泥中出稀土元素的过程优化和动力学研究
Aditya Ranjan Ray1, Bankim Chandra Tripathy2, Sujata Mishra3
1Department of Chemistry, Institute of Technical Education and Research, Siksha'O'Anusandhan Deemed to be University, Khandagiri Square, Bhubaneswar, Odisha, 751030, India.
Scientific reports
|October 21, 2025
概括
使用酸从红泥中回收稀土元素 (REEs) 是可行的. 优化条件实现了90.16%的REE冲洗效率,支持循环经济.
科学领域:
- * 环境化学 环境化学
- * 材料科学 材料科学
- * 化学工程 化学工程
背景情况:
- * 过度开发自然资源需要从二次来源可持续地回收材料.
- *红泥是生产的废弃副产品,含有大量有价值的稀土元素 (REEs).
- *有效的REE回收需要详细的废物表征和目标元素的特异化.
研究的目的:
- *为了优化酸浸出参数从红色泥土中提取REE.
- * 通过一种对环境无害的方法来研究REE漏的动力学.
- * 评估酸作为可持续回收REE的漂水剂的可行性.
主要方法:
- *采用了响应表面方法 (RSM) 与中央复合设计 (CCD).
- *优化化参数包括酸度,温度和时间.
- *动力分析是使用缩小球体模型进行的.
主要成果:
- *最佳的浸出条件:酸2mol/L,343K,240分钟.
- * 实现了最大的REE冲洗效率90.16%.
- *动力学研究表明,扩散控制机制的激活能量为25.10kJ/mol.
结论:
- *酸是一种可行且环保的洗剂,可以在适度条件下从红色泥土中回收REEs.
- *优化过程为关键元素回收提供了有效的途径,增强了资源供应链.
- *这种方法促进了资源效率,并支持循环经济原则.
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