在MnBiBi中的固有永久磁性的原子工程
Uranbaigal Enkhtur1, Dorj Odkhuu2
1Department of Physics, Incheon National University, Incheon, 22012, South Korea.
Scientific reports
|October 21, 2025
概括
研究人员探索了没有稀土的永久磁铁,特别是MnBi. 他们发现,在 (Bi) 位点用 (Ge) 进行兴奋剂增强了磁性,提高了先进磁体应用的稳定性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 计算材料科学科学 计算材料科学
背景情况:
- 低温阶段的MnBi是无稀土永久磁铁的关键材料.
- 它表现出不寻常的磁性异构性和强制性,随着温度的增加而增加.
研究的目的:
- 为了研究MnBi的结构稳定性和磁性,使用各种金属和金属化物替代品.
- 在理论上展示了提高MnBi磁性能的方法.
主要方法:
- 密度函数理论 (DFT) 是一种密度函数理论.
- 密度功能性扰乱理论 (DFPT) 是一个理论.
- 蒙特卡罗模拟的蒙特卡罗模拟
主要成果:
- 在MnBi中,低在平面中的磁晶异构性可以由于Mn原子的迁移和晶格膨胀而重新定向为一个大的单轴异构性.
- 在Bi位点的 (Ge) 替代保留了MnBi相稳定性并增强了内在磁性.
- 预测一个大的单轴磁晶异性质 ([公式:见文本]) 的3.6MJ/m3和库里温度 ([公式:见文本]) 到780K的Ge替代MnBi.
结论:
- 用像Ge这样的非磁性金属化物元素替代MnBi的兴奋剂是一种可行的策略,以提高内在的磁性性能.
- 该研究阐明了通过电子结构修改来扭转磁化和增强异性质的机制.
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