由于与二氧化碳的相互作用而导致的石和多洛米特的孔隙结构变化 - 洞察地质储存的洞察力
Felipe P DE Souza1, Daniel N N Silva1, Cláudio R S Lucas1
1Universidade Federal do Pará, Laboratório de Ciência e Engenharia de Petróleo e Energia, Rua Raimundo Santana Cruz, s/n, Campus Universitário de Salinópolis, 68721-000 Salinópolis, PA, Brazil.
Anais da Academia Brasileira de Ciencias
|October 22, 2025
概括
地质碳储存的有效性取决于岩石的特性. 这项研究表明,二氧化碳改变碳酸盐岩石,富含石的石灰岩比多洛米特更容易扩大孔隙,特别是在液态二氧化碳中.
科学领域:
- 地质化学 地质化学
- 地质地质地质地质地质地
- 石化物理学 石化物理学
背景情况:
- 地质碳储存对于减少二氧化碳排放至关重要.
- 储存形成的石化物理特性对储存的有效性产生了重大影响.
- 碳酸盐岩中的二氧化碳流体相互作用可以改变孔隙性和透性.
研究的目的:
- 研究CO2-碳酸盐相互作用对孔隙结构演变的影响.
- 分析不同CO2流体相和暴露时间的影响.
- 了解矿物学对二氧化碳引起的岩石变化的影响.
主要方法:
- 高分辨率的微型CT成像外样本 (印第安纳石灰岩,西卢里亚多洛米特).
- 样品暴露于碳酸水 (CW) 和超临界CO2 (SCO2) 的情况.
- 在14天和28天内,对孔隙结构变化的定量成像分析.
主要成果:
- 印第安纳州的石灰岩 (富含石) 显示出明显的孔隙扩大和连接性,特别是在CW下.
- 罗纪多洛米特表现出异质和空间受约束的反应性.
- 溶解在液态阶段更明显,表明碳酸的作用.
- 观察到一个非线性多孔性演变趋势 (早期溶解,然后稳定).
结论:
- 矿物学,流体阶段和暴露时间显著控制碳酸盐岩石中二氧化碳引起的变化.
- 了解这些相互作用对于有效地选择和管理地质碳储存地点至关重要.
- 碳酸在二氧化碳储存期间的矩阵降解中起着关键作用.
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