来自核设施的废水自动分析Fe和Ni
Kesheng Hu1, Junqiang Yang2, Haolin Zhou1
1School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, PR China.
Journal of hazardous materials
|October 22, 2025
概括
一个新的自动化系统提供了核废水中铁-55 (Fe) 和-63 (Ni) 的快速现场分析. 这项技术显著提高了效率,并减少了环境监测的辐射暴露.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 核工程 核工程是指核工程.
背景情况:
- 人为55Fe和63Ni是核设施废水中的关键放射性核化物.
- 目前的手动分析方法效率低,劳动密集型,不适合实时监控.
研究的目的:
- 开发一个全自动化系统,快速地在核废水中分析Fe55和Ni63.
- 克服传统手动分析方法的局限性.
主要方法:
- 开发了一种连续注射系统,集成了沉预处理,双列染色学和液体闪检测.
- 使用可编程控制算法来优化系统参数.
- 在50分钟内实现了1L样品的自动处理.
主要成果:
- 实现了高化学产量:96%±3%的Fe和92%±4%的Ni.
- 分析不确定性保持低 (Fe和Ni分别低于6%和7%).
- 该系统有效地消除了矩阵干扰,并展示了强大的性能.
结论:
- 与手动方法相比,自动化系统可显著提高效率并减少辐射暴露.
- 这个平台可以实时对核废物进行放射性监测.
- 该系统可适应在各种场景下分析其他放射性核化物.
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