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用表面活性剂为水中分子太阳能热能储能系统的策略

Lorette Fernandez¹, Helen Hölzel^1,2, Pedro Ferreira¹

¹Department of Chemical Engineering, Universitat Politècnica de Catalunya, EEBE Eduard Maristany 10-14 08019 Barcelona Spain helen.holzel@upc.edu kasper.moth-poulsen@upc.edu.

Green chemistry : an international journal and green chemistry resource : GC

|October 23, 2025

概括

分子太阳能热能储能系统 (MOST) 提供了一个可持续的能源解决方案. 在水基溶液中使用norbornadiene/quadricyclane (NBD/QC) 衍生物的新绿色MOST系统在没有危险溶剂的情况下显示出有希望的性能.

科学领域:

可再生能源储存可再生能源的储存
材料科学材料科学材料科学
绿色化学绿色化学

背景情况:

分子太阳能热能储存 (MOST) 利用太阳光以化学键储存能量.
对于MOST而言,Norbornadiene/四旋旋风 (NBD/QC) 系统是有前途的,但往往需要危险的有机溶剂.
开发更安全的,基于水的MOST系统对于大规模实施至关重要.

研究的目的:

为了研究使用水溶液中的NBD/QC衍生物的新型,更绿色的MOST系统.
在与有机溶剂相比的水基介质中达到高度的NBD/QC.
为了评估这些水性MOST系统的性能.

主要方法:

合成含有蓝和p-基替代的NBD/QC衍生物.
在非离子表面活性剂和水中配制NBD/QC溶液.
在水性介质中NBD/QC溶解性和稳定性的表征.
集成到液体太阳能收集器件中.
在催化触发时释放热量的评估.

主要成果:

在水/表面活性剂混合物中达到高NBD度 (高达1.6M).
在太阳能收集装置中观察到NBD完全转换为QC.
在环境条件下,在催化触发时,温度增加了4.7°C.
在能量密度,光转换和热释放方面,性能与基于托洛的系统相美.

结论:

在水性介质中,NBD/QC衍生物可以有效地用于MOST.
绿色水性MOST系统可以与传统的基于有机溶剂的系统相匹配.
这项研究为更安全,更可持续的大规模MOST应用铺平了道路.

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