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Updated: Jan 14, 2026

Synthesis of Near-Infrared Emitting Gold Nanoclusters for Biological Applications
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Published on: March 22, 2020

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消除π-结合以增强Au (I) 综合体中的友好性相互作用和聚合诱导的光

Andriani Furoida1, Kazuhisa Ozaki1, Ryoko Niimi1

  • 1Department of Applied Chemistry, Ritsumeikan University, Kusatsu 525-8577, Japan. tsutsumi@sk.ritsumei.ac.jp.

Chemical communications (Cambridge, England)
|October 24, 2025
PubMed
概括

这项研究合成了一种黄金 (I) 复合物与非结合联体,实现了强烈的黄色室温光. 这突出了通过增强的金性相互作用设计高效的重金属发射器的新策略.

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para...
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