斯托克斯-爱因斯坦关系的起源在简单的密集液体中
T Oppelstrup1,2, B Sadigh2, S Sastry3
1Cerebras Systems Inc., Sunnyvale, California 94085, USA.
The Journal of chemical physics
|October 24, 2025
概括
我们用一种新的结构放松度量来解释液体中的斯托克斯-爱因斯坦关系. 这表明密度波动和高斯扩散导致了这种普遍的液体动力学相关性.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 统计力学就是统计力学.
- 物理化学 物理化学
背景情况:
- 斯托克斯-爱因斯坦 (SE) 关系连接了液体中的结构松和扩散,但其微观起源仍然不清楚.
- 从宏观水力动力学衍生出的SE关系,在描述微观液体动力学方面具有惊人的效果.
研究的目的:
- 在简单的密集液体中阐明普遍的斯托克斯-爱因斯坦关系的基本起源.
- 引入一种新的,普遍的测量方法来量化N粒子系统中的结构松.
主要方法:
- 配置空间的分解成N! 同等凸多面体来定义一个普遍的结构松措施.
- 使用最小的欧几里德距离来量化配置相关性,在粒子排列上进行优化.
- 使用这个测量和一个随机步行者模型与单个占用约束的总方程的推导.
主要成果:
- 证明SE关系源于两个关键条件:de Gennes缩小 (密度波动仅限于第一个协调) 和高斯扩散.
- 确定de Gennes缩小作为一个关键因素,观察到在低密度流体中被侵犯.
- 承认扩散过程的高斯度作为另一个基本条件,已知在超冷液体中被侵犯.
结论:
- 在密集液体中普遍的斯托克斯-爱因斯坦关系基本上是由密度波动和高斯扩散的限制解释的.
- 该研究提供了一个理论框架,以了解SE关系在低密度和超冷液体中的适用性限制.
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