运动诱导的结晶和旋转的结晶体.
Max Philipp Holl1,2,3, Alina Barbara Steinberg3, Michael Te Vrugt4
1Aalto University, Department of Chemistry and Materials Science, P.O. Box 16100, FI-00076 Aalto, Espoo 00076, Finland.
Physical review letters
|October 25, 2025
概括
活性软物质表现出运动性诱导的相分离和结晶. 本研究探讨了对这些过程的热力学和活性影响,揭示了新的相位图和集群行为.
科学领域:
- 物理 物理学 物理
- 材料科学 材料科学 材料科学
- 软物质物理学 软物质物理学
背景情况:
- 活性软物质显示出运动性诱导相分离 (MIPS) 和结晶.
- 自行粒子形成类似液体或晶体的集群.
- 了解主动与被动影响至关重要.
研究的目的:
- 为了研究被动 (热力学) 和主动 (机动性诱导) 凝结/蒸发和结晶/化之间的相互作用.
- 开发和利用一个更高阶的活性相场晶体模型.
- 分析稳定性和形态相位图.
主要方法:
- 导出一个更高阶的活性相场晶体模型.
- 数字模拟用于研究相位过渡和形态学.
- 稳定性和形态相位图的分析.
主要成果:
- 阶段图揭示了各种阶段的共存和过渡.
- 被动集群可以通过密度独立的活性速度被摧毁.
- 活跃星团可以形成密度依赖的活跃速度.
- 观察到旋转的晶体,包括奇拉状态.
结论:
- 该模型成功地捕捉了软物质中主动和被动力的相互作用.
- 主动速度依赖显著影响集群形成和稳定性.
- 复杂的动态行为,如旋转的性晶体,从模型中出现.
相关概念视频
Crystal Growth: Principles of Crystallization
4.6K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
4.6K
Recrystallization: Solid–Solution Equilibria
2.0K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
2.0K
Polymer Classification: Crystallinity
3.7K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
3.7K


