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Updated: Jan 14, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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合成一个超明亮的Rotaxane带有线程 BODIPY 塞

Matthieu Hicguet1, Olivier Mongin2, Yann R Leroux2

  • 1Univ Rennes, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR6226, F-35000 Rennes, France.

Organic letters
|October 25, 2025
PubMed
概括

合成了一种新型的组装罗塔xane,配有 BODIPY 堵塞. 选择性去除激活了它的光,产生了一个非常明亮和光的分子.

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Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)01:16

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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