碳酸盐托管的斯法莱里特气候变化调节了土壤中的动员
Xin-Yang Li1,2, Juan Liu1, Peng-Jie Hu1
1State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 211135, China. lhwu@issas.ac.cn.
Environmental science. Processes & impacts
|October 27, 2025
概括
采矿从球石中释放 (Cd). 碳酸盐控制Cd的流动性,较高的Ca/S比率通过形成CdCO3.3来减少Cd的释放. 纳米颗粒Cd,通常是CdCO3,决定了Cd在土壤中的移动性.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 土壤科学 土壤科学
背景情况:
- 在矿藏中的球石中的 (Cd) 可以通过采矿颗粒物 (PM) 污染土壤.
- 碳酸盐在球岩气候变化期间对Cd流动性的影响尚未完全理解.
研究的目的:
- 研究土壤中的球石矿石颗粒 (SP) 的Cd调动.
- 在酸性和性土壤中确定固体和水性相之间的Cd分布.
主要方法:
- 在酸性和性土壤中研究了不同Ca/S比率的Cd调动率.
- 使用大量化学数据和传输电子显微镜 (TEM) 分析了CD分布.
主要成果:
- 在低Ca/S比率的酸性和性土壤中观察到类似的Cd调动率.
- 较高的Ca/S比率显著降低了Cd的流动性,促进了CdCO3的形成和封存.
- 纳米颗粒Cd与纳米-Fe和纳米有机碳相关,形成CdCO3纳米材料.
结论:
- 碳酸盐含量显著影响受球石PM影响的土壤中的Cd流动性.
- 含有Cd的纳米材料,特别是CdCO3,是这些环境中Cd调动和封存的关键驱动力.
相关概念视频
Extraction: Advanced Methods
1.1K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.1K
Factors Affecting Solubility
36.6K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
36.6K
Carbonation Shrinkage
441
Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
441
Carbon-dioxide Fixation
628
Carbon dioxide fixation in prokaryotes enables the assimilation of inorganic carbon into organic molecules, supporting biosynthetic pathways, sustaining ecosystems, and contributing to the global carbon cycle. It also has industrial applications in carbon capture and bioproduct synthesis. Autotrophic organisms rely on this process to utilize CO₂ as a carbon source in diverse environments.The Calvin CycleThe Calvin cycle is the most widespread carbon fixation mechanism, primarily used by...
628
Corrosion
28.1K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
28.1K
Corrosion of Reinforcement
496
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
496


