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通过单个实体分析揭示的普鲁士蓝色的缺陷驱动电化学域调制

He Zhang1, Yang Tao1, Lei Pan1

  • 1Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, United States.

Journal of the American Chemical Society
|October 28, 2025
PubMed
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No abstract available in PubMed .

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Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
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Electrogravimetric analysis measures the weight of an analyte deposited electrolytically onto a suitable working electrode. This method involves applying a potential to a pre-weighed electrode submerged in a solution, which results in the desired substance being deposited through reduction at the cathode or oxidation at the anode. The electrode's weight is recorded after deposition, and the difference in weight gives the analyte's weight in the solution.
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