关于康杰克的碳素甲基化修饰及其对钻井液和破裂液的影响的研究
Yongfei Li1,2, Pengli Guo1, Kun Qu1
1Shanxi Province Key Laboratory of Environmental Pollution Control and Reservoir Protection Technology of Oilfields, Xi'an Shiyou University, Xi'an 710065, China.
Gels (Basel, Switzerland)
|October 28, 2025
概括
碳氧甲基化康杰克葡萄甘 (CMKG) 通过改善钻井流体质和破裂流体粘度来增强油田运营. 这种可生物降解的添加剂提供了卓越的稳定性和受控的降解,使其成为一个环保的替代品.
科学领域:
- 石油工程是石油工程中的一个.
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
背景情况:
- 开发新型,环保的油田添加剂至关重要.
- 像康杰克葡萄甘 (KGM) 这样的天然聚合物具有生物降解性和低成本,但水溶性和热稳定性较差.
- 由于KGM的局限性,其在钻井和破裂流体中的应用受到限制.
研究的目的:
- 为了化学修改Konjak葡萄甘 (KGM),以改善其用于油田应用的特性.
- 为了评估改性聚合物的性能,Carboxymethylated Konjac glucomannan (CMKG),作为钻井液添加剂和破裂液加厚剂.
主要方法:
- 对KGM进行碳甲基修改,以引入碳甲基组.
- 评价CMKG作为钻井液添加剂,评估质性质和粘土抑制.
- 评估CMKG作为裂变流体加厚剂,测试粘度,热稳定性,剪切阻力和凝破解性能.
主要成果:
- 在钻井流体中,CMKG形成了一个稳定的3D凝网络,增强了形学和抑制了粘土膨胀.
- 与KGM相比,CMKG在裂变流体中表现出更高的粘度,在高温和剪切下保持完整性.
- 该CMKG系统在300分钟内显示可控降解,满足运行要求.
结论:
- 碳甲基修饰显著提高了KGM的水溶性,稳定性和性能.
- CMKG是一种可行的,环保的添加剂,可提高钻井流体的性能和破裂流体的性能.
- 修改后的聚合物为油田应用提供了更好的风湿控制,稳定性和可降解性.
相关概念视频
Physical Properties of Carboxylic Acid Derivatives
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Intermolecular forces dictate several physical properties such as boiling points, melting points, solubilities, and so forth. They are classified into four types: ionic forces, hydrogen bonds, dipole–dipole forces, and dispersion forces. Ionic forces are the strongest, while dispersion forces are the weakest.
Among the carboxylic acid derivatives, the boiling points of acid chlorides and esters are very similar and are the lowest in the series. Acid anhydrides have slightly higher boiling...
Among the carboxylic acid derivatives, the boiling points of acid chlorides and esters are very similar and are the lowest in the series. Acid anhydrides have slightly higher boiling...
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Physical Properties of Carboxylic Acids
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Carboxylic acids with lower molecular weight exhibit a sharp and unpleasant odor. They also have higher boiling and melting points than analogous compounds, such as aldehydes, ketones, and alcohols.
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Preparation of Carboxylic Acids: Carboxylation of Grignard Reagents
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Carboxylic acids can be prepared by the carboxylation of Grignard reagents (RMgX). This method is convenient for converting alkyl (primary, secondary or tertiary), vinyl, benzyl, and aryl halides to carboxylic acids with one additional carbon than the starting RMgX.
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