在半稀释的聚烯胺水凝中,弹性模块和依赖应变的侧向应变与轴向应变比
Satya Pal1, Thomas E Angelini2, Abir Bhattacharyya1
1Department of Materials Engineering, Indian Institute of Technology, Jodhpur, Rajasthan, 342030, India.
Journal of the mechanical behavior of biomedical materials
|October 28, 2025
概括
使用2D-DIC测量聚烯胺水凝的弹性模量,可以发现应变率不敏感性和功率定律缩放. 这项工作为生物技术应用提供了对不同变形模式下的水凝行为的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 生物技术是生物技术.
背景情况:
- 聚烯胺等合成水凝中的弹性模量调节对于生物技术至关重要.
- 在各种变形下测量软水凝的机械性能存在挑战.
研究的目的:
- 测量聚烯胺水凝的拉力和简单剪切应力-张力反应.
- 为了研究延展率对机械性能的影响.
- 提出一种基于聚合物物理的解释,以解释水凝的行为.
主要方法:
- 使用一种非接触式,二维数字图像相关 (2D-DIC) 技术.
- 在半稀释度下测试完全膨胀的聚烯胺凝.
- 在拉力和简单剪切试验中,应用于从10^-3到10^-1 /s的应变速率.
主要成果:
- 应变场是均的,直到值应变水平.
- 弹性模块通常对拉伸率不敏感,但由于惯性而导致高速率的例外.
- 观察到德·金纳斯c^9/4功率定律对具有凝度的弹性模块进行缩放.
- 凝在小压力时表现出线性弹性,但在更高的拉力压力时变得可压缩,表现出非线性行为.
结论:
- 聚烯胺水凝在小应变时遵循线性弹性,在更高应变时偏离,变得可压缩.
- 简单的剪切反应仍然是线性的,与拉伸反应不同.
- 一个聚合物物理模型将水凝度,网状大小和弹性模块连接起来,解释了依赖应变的应力演变.
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