高压缩球形碳与可调节的丰富孔隙结构,用于高效的储存
Qinghang Chen1,2,3, Qianxiong Wen1,2,3, Chao Li1,2,3
1Institute for Carbon Neutralization Technology, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang, 325035, China.
Advanced materials (Deerfield Beach, Fla.)
|October 29, 2025
概括
工程硬碳阳极为离子电池 (SIB) 提供高容量和密度. 这项研究展示了一种预孔策略,以提高重量计和体积计性能,克服关键的SIB挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硬碳是离子电池 (SIB) 的一个有前途的阳极,因为它具有可调节的孔状结构.
- 对于SIB来说,一个主要的挑战是平衡高压缩密度的储存的孔积.
研究的目的:
- 为高紧缩密度球形硬碳阳极开发一个孔前工程战略.
- 同时提高SIB中的重力度和体积度能力.
主要方法:
- 使用预孔工程策略,制造具有可调节毛孔结构的球形硬碳.
- 研究孔隙结构调节对微观,中观和宏观尺度电化学性能的影响.
主要成果:
- 优化硬碳的可逆容量为375.40 mAh g-1和初始库伦比效率为90.1%.
- 高压缩阳极实现了359.49 mAh g-1的可逆容量和390.30 mAh cm-3.3的体积容量.
- 一个Ah级袋式电池展示了实际的潜力.
结论:
- 孔结构工程对于优化SIB的硬碳阳极至关重要.
- 开发的战略有效地提高了重力计和体积计的能量密度.
- 制造方法显著影响电极结构和储存行为.
相关概念视频
Pore Transport and Ion-Pair Transport
1.1K
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
1.1K
Porosity in Cement Paste
428
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
The balance of water to cement in the mix is...
428
Ionic Crystal Structures
16.8K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.8K


