一个形的,基于三的多元组件金属,用于烯分离
Qian Feng1,2, Ruoqian Zhang1, Zhikai Li1
1State Key Laboratory of Porous Metal Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, P. R. China. mingming.zhang@xjtu.edu.cn.
概括
由于相似的特性,将烯异构体分离起来很困难. 一种新型的形金属有效地将对烯从其同位素中分离出来,具有高选择性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 超分子化学 超分子化学
背景情况:
- 烯异构体具有相似的化学结构和沸点,使它们的分离变得复杂.
- 在化学工业中,高能效地分离异构体是化学工业的一个重大挑战.
研究的目的:
- 开发一种用于选择性分离西异构体的新材料.
- 解决对烯与其同位素的高能效分离的挑战.
主要方法:
- 一个形的,基于三的多元组件金属的合成.
- 使用金属来分离烯异构体.
主要成果:
- 开发的金属体在将帕拉烯从其结构异构体中分离时表现出高的选择性.
- 形状和基于三的结构有助于子的分离效率.
结论:
- 基于三酸的新型金属层为对氧化的选择性和节能分离提供了一个有前途的解决方案.
- 这项工作推进了多孔材料的设计,以挑战同位素分离.
更多相关视频
07:45Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
10.4K
09:45Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
10.8K
相关概念视频
Extraction: Advanced Methods
1.1K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.1K
Ion Exchange
1.1K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.1K
