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在现场自光成像揭示了在多相聚合物中对电树的界面封闭效应.

Chaolu Niu1, Wenxia Sima1, Potao Sun1

  • 1State Key Laboratory of Power Transmission Equipment Technology, Chongqing University, Chongqing, 400044, P. R. China.

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概括

研究人员在电气树损坏区域内观察到跨链聚乙烯 (XLPE) 和 (SIR) 等聚合物中的自光. 这一突破允许纳米级电树的3D成像,帮助绝缘可靠性研究.

关键词:
3D非破坏性表征 3D非破坏性表征自光成像自光成像接口电气树 接口电气树分子构造的分子构造.多相聚合物的多相聚合物.

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科学领域:

  • 多相聚合物接口科学 多相聚合物接口科学
  • 电气绝缘材料 电气绝缘材料

背景情况:

  • 电气损坏树木是绝缘可靠性的关键挑战.
  • 当前技术的空间分辨率有限,阻碍了接口电树的3D可视化.

研究的目的:

  • 开发一种用于在现场3D可视化聚合物中的电树的方法.
  • 研究界面电树的进化和故障机制.

主要方法:

  • 在电树损坏区域内观察非光聚合物 (XLPE,SIR) 的自发光.
  • 同焦点扫描显微镜用于纳米级3D成像和实时监测电树.
  • 分析分子变化 (π-π* 结合,循环素寡合体) 和它们对能量差距 (ΔE) 的影响.

主要成果:

  • 自动光被成功地用于3D成像的电树没有外源的探头.
  • 分子变化 (减少的DE) 在受损的聚合物区域中增强了自发光强度.
  • 在XLPE中,界面封闭效应会影响电树的传播,促进横向扩张.

结论:

  • 开发的自光成像方法为电树的3D可视化提供纳米分辨率.
  • 该技术提供了一个非破坏性评估平台,用于研究多相绝缘系统中的界面故障机制.
  • 了解电树的演变对于提高绝缘可靠性至关重要.