通过氨基聚合物添加剂工程提高纳米过膜选择性,以从盐水中有效提取
Shaofan Duan1,2, Shuai Jiang1,2, Ping Xu1
1Research Center for Membrane and Film Technology, Kobe University, 1-1 Rokkodaicho, Nada, Kobe, 657-8501, Japan.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|October 30, 2025
概括
这项研究引入了一种新的方法,用于增强使用改性纳米过 (NF) 膜从盐水中提取的方法. 改进的膜显示出对的选择性优于的选择性,这对于有效的直接提取 (DLE) 至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 使用纳米过 (NF) 膜的直接提取 (DLE) 是蒸发的可持续替代方案.
- 传统的聚胺 (PA) NF膜由于表面电荷和透性-选择性权衡,具有较差的/选择性.
研究的目的:
- 开发一种可扩展的方法,以提高NF膜中的分离性能.
- 为了提高Li+/Mg2+的选择性,以便从盐水中有效丰富.
主要方法:
- 在界面聚合过程中将聚胺 (PAA) 纳入聚胺 (PA) 膜.
- 膜性质的表征,包括水的透性和离子排斥.
- 用模拟盐水在两阶段的NF过程中测试优化膜.
主要成果:
- 用PAA添加剂合成的优化PA膜显示水透率为12.1 L m-2 h-1 bar-1.
- 化 (MgCl2) 排斥显著增加,从18.8%增加到94.7%.
- 使用优化膜的两阶段NF过程成功地从模拟盐水中净化了.
结论:
- 经PAA修饰的PA膜提供了增强的Li+/Mg2+选择性和高水透度.
- 该战略为DLE应用中高效丰富和净化提供了一个有前途的方法.
- 开发的膜显示了从盐水中可持续回收的工业应用潜力.
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