Supra-3-V 基于简单的二甲烯酸解质的非水性还原流电池
Nicolas Daub1, Xiaotong Zhang2, Nico J L van Rijswijk1
1Molecular Materials and Nanosystems and Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
概括
基替代的铁甲烯提供了一个更简单的合成非水性氧化还原流电池. 虽然观察到最初的稳定性问题,但两个基组显著改善了性能,显示了未来储能解决方案的前景.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 有机化学 有机化学
背景情况:
- 为非水性氧化还原流电池设计有机分子需要平衡氧化还原潜力,可溶性和稳定性.
- 高度的合成复杂性往往阻碍了这些材料的实际,大规模应用.
研究的目的:
- 为了研究基替代的二甲乙二二烯作为潜在的解物,用于氧化还原流电池.
- 评估基替代对基于二甲甲酸的解析物的稳定性和性能的影响.
主要方法:
- 合成基替代的二甲甲.
- 使用这些无氧化物对氧化还原流电池进行电化学测试.
- 密度函数理论 (DFT) 计算以了解反应机制.
主要成果:
- 与单替代衍生品相比,2,5-二甲基甲乙二烯的稳定性得到了改善.
- 使用这些阳解体的流电池达到3V以上,容量保持良好 (>99.8%循环-1).
- 在40 mA cm-2下,能量效率高达77%,超过了许多基解剂.
结论:
- 2,5-二甲基二甲二甲二列为非水性氧化还原流电池的一种有希望的合成可用的解质类.
- 进一步提高溶解度和长期稳定性是实际,大规模实施所必需的.
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