在高压下28K的超导性在石墨间歇化合物中.
Guangchen Ma1,2, Yingying Wang1,3, Zefang Wang2
1Jilin University, State Key Laboratory of High Pressure and Superhard Materials, College of Physics, Changchun 130012, China.
Physical review letters
|October 31, 2025
概括
研究人员在28K和14GPa的碳化 (NaC8) 中发现了超导性,这对于高温超导体来说是一个显著的进步. 这一发现为探索光元素化合物的超导性开辟了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 石墨间化合物 (GIC) 显示出超导性,其中CaC6显示出15.1K超导性.
- 在GIC中研究高温超导的研究已经停滞了近二十年.
- 高阶段GIC中的超导性在很大程度上仍未被探索,重点是第一阶段化合物.
研究的目的:
- 为了研究高阶GIC中的超导性.
- 为了发现新的高温超导材料.
- 探索碳化作为一种潜在的高温超导体.
主要方法:
- 使用阻力下降测量的超导体的实验发现.
- 磁场依赖性研究高达6T.
- 进行X射线衍射和晶体结构预测.
主要成果:
- 在约28 K和14 GPa的临界温度 (Tc) 中观察到碳化的超导性.
- 电阻呈现急剧下降,在磁场下,Tc 显著下降.
- 这种超导材料被确定为第二阶段的GIC NaC8.
- 上临界场 (μ0Hc2(0)) 估计在8.8 T;连贯度长度在~61.2 Å.
结论:
- 实现了长期寻求的高Tc GIC,超越了以前的记录.
- 确定NaC8作为一个具有显著超导性的高阶GIC.
- 在轻元素化合物中开辟了高温超导体的新研究方向.
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