揭示了单晶分层丰富阴极的结构稳定性和电化学特性之间的相关性
Hanisha Ponnuru1, Sagar Dhananjay Jadhav2,3, Michael W M Jones2,3,4
1School of Mechanical, Medical and Process Engineering, Faculty of Engineering, Queensland University of Technology (QUT), Brisbane, QLD, 4001, Australia.
Small (Weinheim an der Bergstrasse, Germany)
|November 3, 2025
概括
单晶,高阴极显示了离子电池的潜力. 这项研究揭示了粒子大小和含量如何影响它们在循环过程中的电化学稳定性和结构演变.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 富含Ni的单晶 (SC) 层状金属氧化物为离子电池提供高容量和降低的.
- 了解它们的电化学行为对于克服诸如不良离子扩散和不稳定的循环等挑战至关重要.
研究的目的:
- 在延长循环过程中调查SC高Ni阴极材料 (NCM 83和NCM 90) 的电化学行为和结构演变.
- 分析阻抗变化,电化学活性表面积 (ECSA) 和材料完整性.
主要方法:
- 电化学循环SCNCM 83和NCM 90在1C (3-4.5V) 的电气循环,长达300个循环.
- 非法拉第克和法拉第克ECSA的测量.
- 微计算机断层扫描 (μ-CT) 用于结构分析和物质损失量化.
主要成果:
- 循环后NCM 90和NCM 83的非法拉达性ECSA增加,在较小的NCM 90颗粒中观察到更大的增加.
- 在减少过程中,NCM 83显示法拉代ECSA增加了34.4%,而NCM 90则减少了61.46%,表明表面重建和微裂纹.
- 与NCM 90 (≈2%) 相比,μ-CT在较大的NCM 83颗粒 (≈4.5%) 中显示了较大的物质损失.
结论:
- 颗粒大小和Ni含量显著影响SC高Ni阴极的表面和结构稳定性.
- 尽管存在微裂纹,但NCM 90显示出比NCM 83更好的材料完整性,这表明较小的颗粒大小可能有利于长期循环性能.
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