在流体催化裂变催化剂的再生过程中污染物转化
Jiawei Bian1, Robin Vogel2, Pengfei Tian3
1State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology-Utrecht University Joint Research Center for Sustainable and Circular Chemistry and Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China.
Angewandte Chemie (International ed. in English)
|November 4, 2025
概括
了解流体催化裂变 (FCC) 再生过程中的气体污染物形成至关重要. 这项研究将焦炭分解与排放联系起来,帮助清洁的炼油厂运营使用可再生原料.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
- 催化剂是一种催化剂.
背景情况:
- 流体催化裂变 (FCC) 对于重型石油炼油至关重要,并且越来越多地采用可再生原料.
- 在FCC过程中催化剂再生产生了由于焦炭沉积而缺乏了解的气体污染物.
- 来自FCC再生的排放影响环境法规和工艺效率.
研究的目的:
- 在FCC再生过程中调查气体污染物的排放特性和形成机制.
- 为了确定焦炭分解和气体污染物形成之间的相关性.
- 为FCC过程中先进的污染物排放预测和控制提供洞察力.
主要方法:
- 在三个工业FCC单元上进行了堆积测试,以监测污染物排放.
- 描述了使用过的FCC催化剂,以确定碳沉积物的组成.
- 使用现场拉曼,操作FT-IR和在线气相FT-IR光谱来进行再生实验.
- 执行密度函数理论 (DFT) 计算以进行机械解释.
主要成果:
- 确定了焦炭分解途径和气体污染物形成之间的关键关系.
- 证明再生气体中的氧含量显著影响焦炭的演变和污染物排放.
- 确定焦炭物种对排放度和形成温度的影响.
- 经过验证的实验结果与DFT计算.
结论:
- 这项研究有助于更好地理解FCC再生过程中气体污染物的形成.
- 这些发现支持改善FCC排放的预测和控制策略.
- 建立了一个比较来自各种化石和可再生原料的污染物形成的基础.
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