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Updated: Jun 26, 2026

High-throughput Synthesis of Carbohydrates and Functionalization of Polyanhydride Nanoparticles
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Published on: July 6, 2012

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用Pd纳米颗粒装载的AMIEN功能化的MIL-101 (Cr) 的合成后修饰,用于可持续的苏苏基合反应

Mehdi Abroudi1, Azadeh Tadjarodi2, Zolfaghar Rezvani3

  • 1Research Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran.

Scientific reports
|November 4, 2025
PubMed
概括

在MIL-101 ((Cr) 金属有机框架功能化与素和装载着纳米颗粒显示高效率在苏子-米亚乌拉合反应. 这些催化剂可重复使用,并且稳定地形成碳-碳键.

关键词:
CC交叉合反应反应MIL-101 (((Cr) 的意思就是说.帕拉纳米粒子是什么意思综合后策略 (PSM) 战略脏是一种腐蚀性.

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Amides to Amines: LiAlH4 Reduction01:20

Amides to Amines: LiAlH4 Reduction

Amide reduction with strong reducing agents like lithium aluminum hydride proceeds through a nucleophilic acyl substitution to form amines. Primary, secondary, and tertiary amides yield primary, secondary, and tertiary amines, respectively.
Amide reduction requires two equivalents of the reducing agent, acting as a source of hydride ions. As shown in the figure, the reaction is initiated with a nucleophilic attack by the hydride ion at the carbonyl carbon to form a tetrahedral intermediate.
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Nitriles to Amines: LiAlH4 Reduction

Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
As shown below, the mechanism involves three steps. Firstly, the hydride ion acting as a nucleophile attacks the nitrile carbon to form an anion. In the second step, a second equivalent of the hydride ion attacks the anion to...
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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction

The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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Cycloaddition Reactions: MO Requirements for Photochemical Activation

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