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Updated: Jan 12, 2026

Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
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Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera

Published on: December 27, 2018

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具有长寿命自由载体的内在产生电荷的聚合物,用于高效的光子转化为的转化

Yunzhi Wang1,2, Partha Maity1,3,4, Yinglu Jia5

  • 1Center of Excellence for Renewable Energy and Storage Technologies (CREST), Physical Science and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia.

Science advances
|November 5, 2025
PubMed
概括

研究人员开发了新的双电缆聚合物纳米粒子,用于高效的单元有机光催化. 这些纳米粒子吸收近红外光并产生长寿命的自由电荷,大大提高了进化性能.

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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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