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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
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相关实验视频

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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机械上坚固的化物电解质用于高性能全固态电池.

Xu Han1,2,3,4, Yang Xu4, Huamei Li5,6

  • 1National Power Battery Innovation Center, GRINM Group Co. Ltd., Beijing, PR China.

Nature communications
|November 5, 2025
PubMed
概括
此摘要是机器生成的。

本研究介绍了一种基于缺陷的硬化方法,用于全固态电池中的化物固体电解质. 控制冷却速度可以提高机械性能,提高电池的弹性和性能.

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态物理 固态物理

背景情况:

  • 所有固态电池都面临来自脆性陶电解质的机械不稳定性.
  • 电解质脆性导致循环过程中电极体积变化的问题,导致故障.

研究的目的:

  • 为化物固体电解质制定基于缺陷的硬化策略.
  • 为了提高全固态电池的机械性能和循环稳定性.

主要方法:

  • 通过操纵冷却速度来增加缺陷密度来控制合成.
  • 机械性能测试 (斯模量).
  • 使用高分辨率传输电子显微镜和同步射辐射衍射进行微结构性表征.

主要成果:

  • 在灭的化物电解质中,缺陷密度增加.
  • 增强了Young的模量和能量吸收能力.
  • 提高了对电极体积波动的适应性,减少了应变引起的降解.

结论:

  • 缺陷增强硬化有效地改善了化物固体电解质的机械性能.
  • 这一战略提高了所有固态电池的整体完整性和性能.
  • 这种方法优化了机械性能,而不会改变电解质的化学成分.