相关实验视频
Updated: Jan 12, 2026

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.8K
基衍生维洛根共价有机框架作为水性-电池的高性能阴极
Gobinda Das1, Rajkiran Shivade2,3, Priyanshi Pandey2,3
1Chemistry Program, New York University Abu Dhabi (NYUAD), Saadiyat Island, Abu Dhabi, PO Box 129188, United Arab Emirates.
Small (Weinheim an der Bergstrasse, Germany)
|November 6, 2025
概括
一种新型的共价有机框架 (COF) 有效地抑制了水性-电池中的多化物穿. 这为这种有前途的储能技术带来了显著提高的容量和长期循环稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性- (Zn-I2) 电池提供高能量密度,低成本和安全.
- 聚酸的穿效应导致容量色和循环性能差,阻碍了实际应用.
研究的目的:
- 开发一种高效的宿主材料,以减轻水性Zn-I电池中的聚酸穿效应.
- 为了提高Zn-I电池的循环稳定性和性能.
主要方法:
- 基于晶体生物的共价有机框架 (TAB-DNP-BP COF) 的合成,使用单的克反应.
- 组装Zn-I2电池,使用一个I2丰富的TAB-DNP-BPCOF阴极.
- 电化学测试用于评估特定容量,循环稳定性和性能.
主要成果:
- TAB-DNP-BP COF有效地限制了物种和静电捕获的聚化物,抑制了迁移.
- 带有TAB-DNP-BP COF@I2阴极的Zn-I电池在0.5°C时达到337mAh的高特异容量.
- 经过5000个循环证明了异常的循环稳定性,性能优于其他报告的宿主材料.
结论:
- 离子COF显示出稳定电池中化学的巨大潜力.
- 开发的TAB-DNP-BP COF为高性能,耐用水性Zn-I电池提供了一个有前途的战略.
相关概念视频
Voltaic/Galvanic Cells
62.9K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
62.9K
Formation of Complex Ions
25.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
25.6K
Batteries and Fuel Cells
30.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.7K

