可切换线性磁电电的设计和理论通过铁电在I型多铁电中
Hui-Min Zhang1, Cheng-Ao Ji1, Tong Zhu2
1Southeast University, Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Nanjing 211189, China.
Physical review letters
|November 7, 2025
概括
我们发现了多铁体中非挥发性磁电 (ME) 合的两个途径,由旋转空间对称驱动. 这些发现为先进材料中强大的ME效应提供了设计原则.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
背景情况:
- 多铁材料表现出多个铁序,磁电 (ME) 合使磁力通过电场控制磁力,反之亦然.
- 传统上,I型多铁体,其中磁性和铁电由独立的机制产生的,显示ME合较弱.
- 异磁材料是一种表现出共存的反铁磁性和铁电性的子集,为ME现象提供了新的途径.
研究的目的:
- 从理论上研究I型多铁体的磁电合机制,包括变磁和铁磁系统.
- 制定一套实现非挥发性ME合的通用方案.
- 确定多铁材料中强大的ME效应的设计原则.
主要方法:
- 第一原则 电子带结构计算,包括旋转轨道合.
- 一个第一个原则框架来计算ME响应.
- 旋转空间组理论分析,以了解对称性指定的机制.
主要成果:
- 确定了两个不同的,相互排斥的非挥发性ME合路径,由旋转空间对称性支配.
- 路径1:在互空间中切换旋转分裂或旋转动量锁定 (与变磁多铁体相关).
- 途径2:通过电极化逆转切换实时空间磁化,从而产生可切换的线性ME张力元件.
结论:
- 该研究提供了一个实现非挥发性ME合在I型多重铁器中的通用方案.
- 建立了控制强大的非易失性ME效应的一般设计原则.
- 建议热力学稳定的化合物用于这些机制的实验验证.
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