从水溶液中高效地封存Ni (II) 和Cr (III) 离子,使用基于泡和非泡金属的地质聚合物
Fatma A Mohammed1, Sara H Abdullah2, Essam A Kishar2
1Chemistry Department, Faculty of Women for Arts, Science and Education,, Ain Shams University, Cairo, 11757, Egypt. fatmaselim93@yahoo.com.
Scientific reports
|November 10, 2025
概括
这项研究开发了一种新型的泡地质聚合物吸收剂,由甲和飞灰制成,用于有效地从废水中去除Ni (II) 和Cr (III) 等重金属. 与现有吸附剂相比,这种创新的材料表现出优越的吸附能力和去除效率.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 无机化学 无机化学
背景情况:
- 由于重金属的毒性和持久性,它们对环境和健康构成重大风险.
- 在水溶液中有效地消除重金属污染对环境保护至关重要.
- 对于特定的重金属,现有的吸附剂往往在容量,成本或效率上有局限性.
研究的目的:
- 开发和描述用于Ni (II) 和Cr (III) 清除的新型泡和非泡地质聚合物复合材料.
- 评估开发的地质聚合物吸附剂的吸附性能,动力学和热力学.
- 为了比较新型地质聚合物吸附剂与现有材料的有效性.
主要方法:
- 地质聚合物复合材料是用80%的甲和20%的飞灰合成的.
- 进行了吸附实验,以确定吸附能力和去除效率.
- 在吸附前和之后使用了特征化技术 (SEM,FTIR,BET,XRD).
主要成果:
- 这种发泡地质聚合物具有较高的最大吸附能力:Ni (II) 的最大吸附能力为38.46 mg/g,Cr (III) 的最大吸附能力为39.42 mg/g.
- 在最佳条件下,最大的去除效率达到Ni (II) 91.67%和Cr (III) 97.21%.
- 吸附遵循伪二次动力学,并符合弗洛伊德利希等温模型,表明化学吸附.
结论:
- 开发的发泡地质聚合物复合物是一种高效和经济高效的吸附剂,用于Ni (II) 和Cr (III) 的去除.
- 这种材料与活性炭,天然化物和基于金属的地质聚合物相比,表现出更高的性能.
- 这些发现支持使用这种新型地质聚合物用于工业废水整治.
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