在相互连接的多孔环境中进行电动纳米粒子传输:解空腔逃逸和定向偏差
Anni Shi1, Siamak Mirfendereski1, Ankur Gupta1
1Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, CO 80309.
概括
在多孔介质中纳米粒子运输是复杂的. 弱电场通过扩散加速纳米粒子从空洞中逃逸,但方向运动只发生在更强的电场中,揭示了力量平衡.
科学领域:
- 合体和表面科学科学
- 运输现象 运输现象
- 纳米技术纳米技术
背景情况:
- 纳米粒子在多孔介质中的电动运输对于分离技术至关重要.
- 在3D多孔空间中理解边界场合是具有挑战性的.
研究的目的:
- 在不同电场下的3D多孔介质中研究纳米粒子运输动力学.
- 为了阐明布朗运动,电泳和电流之间的相互作用.
主要方法:
- 超分辨率3D跟踪单个纳米粒子在相互连接的空洞.
- 计算机模拟模型纳米粒子动力学 (Péclet数分析).
主要成果:
- 洞穴逃逸时间在弱电场 (2V/cm) 时显著减少,增强了扩散.
- 纳米粒子运动的方向偏差在低电场时可以忽略不计,但在7V/cm时显著.
- 在较低的Péclet数下,运输是随机的,由协调的电泳和电宇宙流驱动,产生.
结论:
- 在狭窄的多孔环境中,布朗运动,电泳力和电流之间存在着微妙的平衡.
- 获得的洞察力可以优化电动力学分离,色谱柱,膜和纳米货物交付.
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