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Updated: Jan 11, 2026

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
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和-碳-化物强合支持增强酸性水氧化

Xueru Zhao1, Tianyou Mou1, Jesse Long1

  • 1Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, United States.

Journal of the American Chemical Society
|November 11, 2025
PubMed
概括

新的-碳-化物 (BCN) 支持的 (Ir) 催化剂在酸性条件下显著提高了氧化演化反应 (OER) 的性能. 伊尔/BCN-75催化剂在质子交换膜水电解 (PEMWE) 中表现出卓越的活性和稳定性.

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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The reaction between a Brønsted-Lowry acid and water is called acid ionization. For example, when hydrogen fluoride dissolves in water and ionizes, protons are transferred from hydrogen fluoride molecules to water molecules, yielding hydronium ions and fluoride ions:
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