超级电容器的无粘合剂金属有机框架核心外阵列
Liuliu Zhang1,2, Fujuan Luo1, Cui Yang3,4
1School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China. taokai@nbu.edu.cn.
Dalton transactions (Cambridge, England : 2003)
|November 12, 2025
概括
金属有机框架 (MOF) 被探索为超级电容器 (SC) 的先进电极材料. 本综述强调了基于MOF的核心外阵列,解决了用于改进能源存储的导电性和稳定性挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- 超级电容器 (SC) 对储能至关重要,其中电极性能是关键.
- 金属有机框架 (MOF) 作为电极材料具有前景,但面临导电性和稳定性问题.
- 无粘合剂的MOF/MOF衍生数组和基于MOF的核心外复合材料提供了解决方案.
研究的目的:
- 审查基于MOF的SC电极核心外混合阵列的合成策略.
- 要总结MOF衍生在核心架构中的使用.
- 讨论无粘合剂核心外阵列电极的挑战和解决方案.
主要方法:
- 对基于MOF的核心外数组现有文献的审查.
- 合成策略的分类:MOFs在过渡金属氧化物 (TMO) 阵列和反应硬模板上.
- 分析MOF衍生品作为核心或外组件.
主要成果:
- 基于MOF的核心外混合阵列是先进的SC电极的一个有希望的策略.
- 涉及TMO数组和硬模板的合成路线是有效的.
- MOF衍生品在核心外结构中提高了性能.
结论:
- 基于MOF的无粘合剂核心外阵列的合理设计对于克服局限性至关重要.
- 复合材料中的协同效应导致了增强的能量储存.
- 解决稳定性和导电性挑战是未来SC发展的关键.
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