在使用温度条件下,聚合物改性水泥混凝土 (PCC) 的结构与性能关系
Alexander Flohr1, Savitha Devarajamohalla Narayana1, Luise Göbel1
1F. A. Finger-Institute for Building Materials Science, Bauhaus-Universität Weimar, 99423 Weimar, Germany.
Materials (Basel, Switzerland)
|November 13, 2025
概括
聚合物修饰对基于水泥的材料产生影响,随着温度升高,强度下降. 低温 (-20°C) 在聚合物改性砂和混凝土中,由于孔水结,导致硬化.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 聚合物化学 聚合物化学
背景情况:
- 聚合物修饰是优化水泥材料 (如砂和混凝土) 的关键.
- 添加聚合物显著改变了新鲜和硬化的特性.
- 了解温度影响对于材料性能至关重要.
研究的目的:
- 研究三种不同聚合物分散剂修改的水泥糊,砂和混凝土的时间依赖性质.
- 分析服务范围内的不同温度对这些属性的影响.
- 在热应力下阐明结构属性关系.
主要方法:
- 系统的,逐步的实验活动.
- 测试三种不同的聚合物分散的水泥糊,砂和混凝土.
- 在不同的温度下评估性能,包括-20°C.
主要成果:
- 聚合物修改显著影响了硬化水泥基材料的行为.
- 强度和抗变形能力通常随着温度的增加而下降,在聚合物改性材料中更是如此.
- -20°C引起了机械行为的显著变化,特别是由于孔水结而导致的屈曲强度和早期度.
结论:
- 聚合物改性水泥基材料表现出内在的温度依赖性行为.
- 在低温下结孔水会导致硬.
- 结果提供了对材料性能在服务温度的关键见解.
关键词:
新鲜和硬化材料的特性.补水动力学是指水的动力学.微观结构的微观结构砂和混凝土的使用.聚合物修饰的聚合物修饰聚合物修饰的水泥糊是聚合物修饰的水泥糊.服务温度范围的服务温度范围.结构财产关系的结构.更多相关视频
相关概念视频
Cold Weather Concreting
343
When freshly poured concrete is exposed to freezing temperatures before it has set, the water within the concrete can freeze. This expansion disrupts the setting process, delays chemical reactions necessary for hardening, and increases the volume of pores within the hardened concrete, which weakens its overall structure. If the concrete manages to reach an appreciable strength before it freezes, the damage can be somewhat mitigated.
To counteract the negative impacts of cold weather, ensuring...
To counteract the negative impacts of cold weather, ensuring...
343
Types of Cement I
333
Portland cement comes in several types, each with distinct properties and applications based on their chemical composition and hydration characteristics:
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
333
Hot Weather Concreting
288
Concreting at elevated temperatures accelerates the hydration process, leading to quicker setting but potentially reducing the long-term strength of the concrete structure. Additionally, low air humidity fosters rapid moisture loss from the concrete, resulting in reduced workability, pronounced plastic shrinkage, and a higher likelihood of crazing.
Mitigating the heat increase in concrete can be economically achieved by shading aggregate stockpiles to prevent heating from solar radiation,...
Mitigating the heat increase in concrete can be economically achieved by shading aggregate stockpiles to prevent heating from solar radiation,...
288
Frost Resistant Concrete
358
Concrete's susceptibility to frost damage during freeze-thaw cycles demands strategic measures to enhance its frost resistance. Employing techniques like air entrainment, adjusting the water-cement ratio, proper curing, and selecting appropriate aggregates are essential.
Introducing microscopic air bubbles into the concrete mix through air entrainment creates small voids that accommodate ice expansion, thereby reducing internal pressures and preventing cracking. The optimal amount of...
Introducing microscopic air bubbles into the concrete mix through air entrainment creates small voids that accommodate ice expansion, thereby reducing internal pressures and preventing cracking. The optimal amount of...
358
Mass Concreting
313
Mass concreting refers to the process of placing large volumes of concrete, such as in gravity dams. The heat generated during the cement hydration process and differential cooling rates within the concrete mass can lead to a temperature gradient, which can result in thermal cracks in the concrete mass.
To reduce the risk of such cracking, the concrete mix may incorporate low-heat cement and pozzolans to reduce the temperature rise. Pre-cooled angular aggregates and water-reducing admixtures...
To reduce the risk of such cracking, the concrete mix may incorporate low-heat cement and pozzolans to reduce the temperature rise. Pre-cooled angular aggregates and water-reducing admixtures...
313
Strength and Heat of Hydration
634
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
634


