由TbCoSi2中的结构相变引起的巨大的平面内收缩.
Lulu Liu1,2,3, Dinghui Wang4, Shoutao Zhang5
1School of Electronic Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China.
Materials (Basel, Switzerland)
|November 13, 2025
概括
研究人员发现TbCoSi2由于结构相位过渡而表现出显著的平面收缩. 这种基于金属的材料在先进的应用中提供了精确的热膨胀控制的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 基于金属的材料的高热膨胀限制了先进的应用.
- 负热膨胀 (NTE) 材料为热膨胀调节提供了解决方案.
- 金属间化合物是NTE材料研究的一个关键领域.
研究的目的:
- 研究多晶TbCoSi2.2的热膨胀特性.
- 确定观察到的热膨胀背后的结构和磁力机制.
- 探索TbCoSi2在精确的热膨胀控制方面的潜力.
主要方法:
- 温度依赖的X射线衍射 (XRD) 和瑞特维尔德精细化.
- 宏观的磁性测量. 宏观的磁性测量.
- 第一原则计算.第一原则计算.
主要成果:
- 多晶TbCoSi2在223K和298K之间显示出3%的平面收缩.
- 结构阶段过渡到低温Pbcm空间群驱动a轴收缩和平面内收缩.
- 在13.7K以下观察到的抗铁磁结构,独立于结构相位过渡.
结论:
- TbCoSi2具有显著的负热膨胀特性.
- 材料的热膨胀主要是由结构变化驱动的.
- TbCoSi2是一种弱磁性材料,适用于单轴热膨胀控制.
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