向离子电池的防火聚合物电解质:电解质设计和结构设计的策略
1Department of Physics and Semiconductor Science, Gachon University, Seongnam-si 13120, Republic of Korea.
Polymers
|November 13, 2025
概括
更安全的离子电池至关重要. 本综述探讨了使用添加剂,纳米尺度填充剂和分层结构来提高聚合物电解质的阻燃性,以提高电池的安全性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 离子电池 (LIB) 面临着易燃液体电解质的安全风险.
- 聚合物电解质提供了更好的热稳定性,但仍然可能构成火灾危险.
- 提高阻燃性是释放聚合物电解质全部潜力的关键.
研究的目的:
- 审查近期改善聚合物电解质阻燃性方面的进展.
- 评估各种增强阻燃性的策略及其对电池性能的影响.
- 为开发更安全,高性能电池提供见解.
主要方法:
- 将阻燃剂添加到聚合物矩阵中.
- 添加纳米级填充剂以增强热阻.
- 用多层或混合聚合物膜结构作为热屏障的设计.
主要成果:
- 各种策略有效地提高了聚合物电解质的阻燃性.
- 提高阻燃性必须与离子导电性和电池整体性能保持平衡.
- 多层/混合结构显示出作为有效的热屏障的前景.
结论:
- 在提高聚合物电解质的安全性方面取得了重大进展.
- 需要进一步的研究,以解决固态电池的持久安全挑战.
- 开发固有的阻燃聚合物电解质对于下一代电池至关重要.
相关概念视频
Batteries and Fuel Cells
30.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.7K
Ionic Bonding and Electron Transfer
48.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
48.6K


