在回收的含化合物中减少硫扩散,以提高拉力强度
Stefan Frosch1, Volker Herrmann1, Fabian Grunert2
1Faculty of Plastics Engineering and Surveying, Technical University of Applied Sciences Würzburg-Schweinfurt, 97070 Würzburg, Germany.
Polymers
|November 13, 2025
概括
将退役回收成磨砂 (GR) 受到硫扩散的限制. 预先化基层可以防止这种扩散,大大改善了回收化合物的机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续工程 可持续工程
背景情况:
- 废旧的回收对于行业的可持续性至关重要.
- 目前的方法,如去火山化,热解,并使用磨砂 (GR) 有局限性.
- 从矩阵中向GR颗粒扩散的硫减少了回收的机械性能.
研究的目的:
- 研究一种减少硫扩散到磨砂颗粒的方法.
- 改进含有磨砂的回收化合物的机械性能.
- 提高回收在苛刻应用中的利用率.
主要方法:
- 在加入磨砂之前先先化绿色的基质材料.
- 复合和化预化基质材料用磨砂.
- 评估由此产生的火山化的机械性能.
主要成果:
- 预火山化有效地减少了从矩阵到磨砂颗粒中的硫扩散.
- 与未经预火山化相比,含有地面的火山化物表现出明显改善的机械性能.
- 矩阵的交联密度得到了更好的维护,从而提高了性能.
结论:
- 通过预硫化矩阵来阻止硫扩散是一种可行的策略,以提高回收的质量.
- 这种方法可以显著增加磨砂的价值和应用范围.
- 虽然目前实验室规模,这种方法提供了在回收工业应用的潜力.
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