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从准备状态到循环条件,量化粘合剂/活性物质界面断裂性质的演变
Akshay S Pakhare1, Gordon H Waller2, Siva P V Nadimpalli1
1Department of Mechanical Engineering, Michigan State University, East Lansing, Michigan 48824, United States.
概括
电池接口故障是一个主要的挑战. 这项研究量化了电解质和循环如何降低粘合剂-接口强度,这对于可充电电池性能至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 在可充电电池中,粘合剂活性材料接口故障至关重要,特别是在高体积变换材料中.
- 接口属性从制造到运行循环的过程中显著演变.
研究的目的:
- 使用临界能量释放率 (Gc) 来量化模型PVdF/Si接口的接口故障行为.
- 为了研究电解质和电化学循环对PVdF/Si接口的Gc的影响.
主要方法:
- 使用了基于迈克尔森干扰仪的光学设置,与电化学电池内的囊泡测试集成.
- 在不同条件下 (干燥,电解质暴露,循环) 量化PVdF/Si接口的临界能量释放率 (Gc).
主要成果:
- 干燥的PVdF/Si接口Gc是0.55±0.10 J m−2.2. 这就是干燥的PVdF/Si.
- 引入电解质将Gc降低了40%至0.31 ± 0.10 J m−2.2.
- 电化学循环还将Gc进一步降低21%,至0.26 ± 0.03 J m-2,裂在接口上发生扩散.
结论:
- 电解质溶剂和电化学循环显著降低了粘合剂-接口强度.
- Gc的减少归因于改变的界面粘合环境.
- 接口断裂性独立于样品几何形状,仅取决于接口材料.
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