在酸电解质中升起Au(111) 重建的动力学
Gary S Harlow1,2,3, Weronica Linpé1, Sebastian Pfaff4
1Division of Synchrotron Radiation Research, Lund University, Sweden. edvin.lundgren@fysik.lu.se.
Physical chemistry chemical physics : PCCP
|November 14, 2025
概括
黄金 (Au) 的条纹重建111) 表面变化与应用的电潜. 表面X射线衍射揭示了潜在循环期间黄金表面结构的缓慢,连续的变化,取决于扫描速率.
科学领域:
- 电化学 电化学 电化学
- 表面科学是一门学科.
- 材料科学 材料科学 材料科学
背景情况:
- 在Au(111) 表面表现出一个众所周知的条纹的p × √3重建.
- 电极表面重组是电化学中的一个关键现象.
- 在应用潜力下了解表面动态对于电化学应用至关重要.
研究的目的:
- 在应用电位循环下研究Au(111) 表面重建的动态.
- 为了确定潜在的扫除率对表面重组的影响.
- 为了描述鱼骨重建的升起和改造.
主要方法:
- 在现场高能表面X射线衍射 (HESXRD).
- 电化学电位在0.06V和0.86V之间循环,与RHE相比.
- 在0.1M HClO4电解质中,控制的潜在扫描速率为5mV/s和2mV/s.
主要成果:
- 鱼骨重建的单元细胞逐渐随着积极潜力的增加而延长.
- 重建完全提升到大约0.7V以上.
- 观察到重建升级和改造的动态是缓慢和持续的.
- 较慢的潜在扫除率导致了在更积极的潜力下进行提升和改革.
结论:
- Au(111) 表面重建表现出缓慢的,潜在依赖的动态.
- 潜在的扫除率显著影响观察到的重组潜力.
- 这些发现为电极表面的动态行为提供了见解.
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