离子强度调节了酸盐涂层的银纳米颗粒对复杂环境矩阵中的大夫尼大菌的尺寸控制生态毒性
Ping Luo1, Zhenghao Xu1, Jiageng Zhang2
1School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou, 221116, People's Republic of China.
Environmental geochemistry and health
|November 15, 2025
概括
离子强度显著影响银纳米粒子 (AgNP) 对水生生物的毒性. 较高的离子强度最初通过促进聚合来降低AgNP的毒性,但超高水平可以通过颗粒分解来增加它,这表明当前的法规可能低估了风险.
科学领域:
- 环境化学环境化学
- 生态毒理学 生态毒理学
- 纳米技术纳米技术
背景情况:
- 银纳米粒子 (AgNPs) 对水生生物有暴露风险.
- 离子强度 (IS) 对复杂环境矩阵中的AgNP毒性的影响尚不清楚.
- 当前的环境法规可能低估了AgNP的风险.
研究的目的:
- 研究离子强度对酸盐涂层AgNP (Cit-AgNP) 的聚合,溶解和生态毒性的影响.
- 为了评估Cit-AgNP对Daphnia magna在垃圾填埋场液和家用污水中的毒性.
- 评估目前对AgNPs的监管限制的充分性.
主要方法:
- 检查了Cit-AgNP聚合,溶解和生态毒性,在垃圾填埋污水和家用污水中的不同离子强度 (10-700毫米) 中.
- 作为测试生物体使用了Daphnia magna.
- 测量抑制率和粒子大小变化.
主要成果:
- 增加的IS (10-450mM) 降低了Cit-AgNP的zeta潜力,促进聚合和降低生态毒性 (13-100%的抑制).
- 在超高IS (450-700毫米) 时,聚合物大小减少,导致毒性增加.
- 由于AgClx复合物的形成,银溶解对生态毒性贡献最小.
结论:
- 离子强度是控制复杂水生环境中AgNP生态毒性的关键因素.
- 在低于监管限度的度下观察到的毒性突显了对AgNP风险的潜在低估.
- 聚合和分解AgNP的动态显著影响生物可用性和毒性.
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