从拉曼和NIR光谱中去除溶剂效应,以便在基于溶解的回收过程中在多溶剂系统中实时监测溶解的聚烯含量
Sofiane Ferchichi1, Nida Sheibat-Othman2, Maud Rey-Bayle3
1IFP Energies Nouvelles, Rond-Point de l'échangeur de Solaize, Solaize, 69360, France; Universite Claude Bernard Lyon 1, LAGEPP, UMR 5007 CNRS, Villeurbanne, 69622, France; Universite Claude Bernard Lyon 1, CP2M, UMR 5128, CNRS, Villeurbanne, 69616, France.
Analytica chimica acta
|November 15, 2025
概括
一种新方法使用光谱技术在回收过程中实时监测溶解的聚烯度. 这种技术适用于各种溶剂,提高塑料回收效率和材料回收.
科学领域:
- 聚合物科学 聚合物科学
- 分析化学 分析化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 聚烯回收对于可持续性至关重要.
- 精确的实时监测溶解聚烯度是一个挑战.
- 溶剂的选择会影响溶解效率和回收结果.
研究的目的:
- 开发一种实时监测方法来检测溶解聚烯度.
- 为了使多种溶剂,包括新溶剂,能够进行监测.
- 提高聚烯溶液回收的效率和适用性.
主要方法:
- 现场拉曼和近红外 (NIR) 光谱仪用于实时监测.
- 部分最小平方 (PLS) 回归用于单溶剂模型开发.
- 对于一个通用的多溶剂模型的外部参数正对称 (EPO).
主要成果:
- 成功开发单溶剂模型来预测溶解的聚烯度.
- 创建了一个通用的多溶剂模型,适用于各种溶剂.
- 证明了在模型训练中未使用的溶剂中的聚烯度的监测能力.
结论:
- 开发的方法允许对溶解的聚烯进行可靠的实时监测.
- 多溶剂模型增强了聚烯回收的灵活性和工业适用性.
- 这种方法有助于改善塑料回收过程中的工艺控制和材料回收.
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