在微相分离区块共聚合物电解质中的封闭效应 - 导电性和结晶性

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Updated: Jan 6, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
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Michael Patrick Blatt1,2, Stephanie Posedel1,2, Kyoungmin Kim1,2

  • 1Department of Chemical and Biomedical Engineering, Florida A&M University-Florida State University (FAMU-FSU) College of Engineering, Tallahassee, FL 32310, USA. dhallinan@eng.famu.fsu.edu.

Soft matter
|November 17, 2025
PubMed
概括

聚合物电解质中的离子导电性取决于形态学. 曲线形态增强导电性,而状形态降低导电性,为固态电池设计提供了洞察力.

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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