加速碳化对MSWIFA中有害元素的泄漏的影响
Qiang Zhou1,2,3, Yuanyuan Zhai1,3, Bo Xing1,3
1School of Chemical Engineering, Sichuan University of Science and Engineering, No. 519, Huixing Road, Ziliujing District, Zigong City, Sichuan Province 643000, China.
ACS omega
|November 17, 2025
概括
城市固体废物焚烧飞灰 (MSWIFA) 可以封存碳,但有害元素漏是令人担忧的. 添加CaO提高了碳化效率,并通过减少有害元素漏来稳定MSWIFA.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 城市固体废物焚烧飞灰 (MSWIFA) 是一种潜在的碳捕集材料.
- 在MSWIFA碳化过程中,有害元素的浸出需要仔细考虑,以确保安全应用.
研究的目的:
- 研究四种不同的MSWIFAs的物理化学特性,碳化效率和有害元素漏.
- 评估碳化对Pb,Ba,Se,Cd和Cr.漏行为的影响.
- 评估CaO添加在增强MSWIFA碳化和稳定有害元素方面的有效性.
主要方法:
- 对四个不同的MSWIFAs进行选.
- 物理化学性质的分析.
- 碳化效率的测量.
- 对重金属 (Pb,Ba,Se,Cd,Cr) 的漂水试验.
- 在MSWIFA中添加5%的CaO的实验.
主要成果:
- 所有的MSWIFA都显示出高碳化效率 (17.2-27%).
- 碳化减少了Pb,Ba和Se的漏,但增加了Cd的漏.
- 碳化对Cr的漏没有显著的影响.
- 添加5%的CaO使碳化效率提高了16.6%,并显著减少了有害元素的漏.
结论:
- MSWIFA碳化可以隔离碳,并抑制某些元素的浸出.
- 在MSWIFA碳化过程中,Cd漏是令人担忧的.
- 添加CaO是一种可行的策略,可以提高碳化效率,稳定MSWIFA,减少有害元素漏.
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