基于弗雷泽-苏苏基解卷法对碳酸的热危害和动力学研究
Yike Wang1, Zhiyu Wang1,2, Suijun Yang1,2
1College of Metrology Measurement and Instrument, China Jiliang University, Hangzhou 310018, China.
ACS omega
|November 17, 2025
概括
碳酸 (SPC) 的分解包括两个外热步骤. 动力分析揭示了每个步骤的不同激活能量和预指数因子,这对于理解其热危险至关重要.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
背景情况:
- 碳酸 (SPC) 是一种强大的氧化剂,用于清洁和环境应用.
- 它的外热分解带来了显著的热失控和火灾风险.
- 了解SPC的热分解动力学对于安全的处理和储存至关重要.
研究的目的:
- 为了研究碳酸 (SPC) 的热分解动力学.
- 为了解构重叠的反应峰值,并确定每个步骤的动力参数.
- 评估与SPC分解相关的热危害.
主要方法:
- 使用差分扫描热量计 (DSC) 获取热分解数据.
- 弗雷泽-苏祖基 (FS) 函数用于解卷重叠的DSC峰值.
- 动力参数 (激活能量,预指数因子) 用已建立的模型 (Avrami-Erofe'ev A4,Šesták-Berggren SB) 确定了每个分解步骤.
主要成果:
- 在SPC的热分解过程中,确定了两个不同的连续反应步骤.
- 动力分析给出了两个步骤的特定激活能量和预指数因子.
- 预测的分解行为与实验数据一致,验证了运动参数.
- 确定了包括SADT在内的关键热危险温度.
结论:
- 该研究为SPC的两步热分解提供了详细的动力参数.
- 计算的热危险温度 (TD8,TD24,SADT) 提供了关键的安全数据.
- 这些发现支持建立安全的储存温度和优化SPC的运输策略.
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